A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H-2 and diethylamine

Authors
Schmid, L Rohr, M Baiker, A
Citation
L. Schmid et al., A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H-2 and diethylamine, CHEM COMMUN, (22), 1999, pp. 2303-2304
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
1999
Pages
2303 - 2304
Database
ISI
SICI code
1359-7345(1999):22<2303:AMRSHA>2.0.ZU;2-W
Abstract
A mesoporous ruthenium silica hybrid aerogel containing well dispersed bide ntate RuCl2[Ph2P(CH2)(3)PPh2](2) complexes, synthesized using a sol-gel met hod, affords turnover frequencies up to 18400 h(-1) and 100% selectivity fr om CO2, H-2 and diethylamine for the formation of N,N-diethylformamide.