Synthesis and structures of a triply-fused incomplete-cubane cluster [{(eta(5)-C5Me5)WS3}(3)Cu-7(MeCN)(9)](PF6)(4) and a 2D polymer [(eta(5)-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 (pz = pyrazine)

Authors
Lang, JP Kawaguchi, H Tatsumi, K
Citation
Jp. Lang et al., Synthesis and structures of a triply-fused incomplete-cubane cluster [{(eta(5)-C5Me5)WS3}(3)Cu-7(MeCN)(9)](PF6)(4) and a 2D polymer [(eta(5)-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 (pz = pyrazine), CHEM COMMUN, (22), 1999, pp. 2315-2316
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
1999
Pages
2315 - 2316
Database
ISI
SICI code
1359-7345(1999):22<2315:SASOAT>2.0.ZU;2-6
Abstract
The reaction of PPh4[(eta(5)-C5Me5)WS3] with 3 equiv. of [Cu(MeCN)(4)]PF6 i n MeCN yielded an unusual high nuclearity W/Cu/S cluster [{(eta(5)-C5Me5)WS 3}(3)Cu-7- (MeCN)(9)](PF6)(4) 1, which in turn gave rise to a 2D polymer [( eta(5)-C5Me5)WS3Cu3Cl(MeCN)(pz)]PF6 2 upon treatment with pyrazine in MeCN in the presence of LiCl.