Metallocene adsorption on clean Si(111) and CaF2/CaF1/Si(111) substrates ha
s been investigated with scanning tunneling microscopy. The surface chemica
l composition is found to strongly change the adsorption site selectivity,
leading to an enhanced edge selectivity on modified substrates. Templates w
ith well-defined local chemical reactivity have been created via self-assem
bly. The selective adsorption of metallocenes on such tailored substrates f
acilitates patterning ordered arrays of magnetic nanowires and stripes on t
he single digit nanometer scale. (C) 1999 American Institute of Physics. [S
0021-8979(99)01822-8].