X-ray photoelectron spectroscopy analysis of GaN/(0001)AlN and AlN/(0001)GaN growth mechanisms

Citation
Sw. King et al., X-ray photoelectron spectroscopy analysis of GaN/(0001)AlN and AlN/(0001)GaN growth mechanisms, J APPL PHYS, 86(10), 1999, pp. 5584-5593
Citations number
75
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF APPLIED PHYSICS
ISSN journal
00218979 → ACNP
Volume
86
Issue
10
Year of publication
1999
Pages
5584 - 5593
Database
ISI
SICI code
0021-8979(19991115)86:10<5584:XPSAOG>2.0.ZU;2-1
Abstract
The mechanisms of growth of GaN on AlN and AlN on GaN via gas source-molecu lar beam epitaxy with NH3 as the nitrogen source have been investigated usi ng x-ray photoelectron spectroscopy, low energy electron diffraction, and A uger electron spectroscopy. The growth of GaN on AlN at low temperatures (6 50-750 degrees C) occurs via a Stranski-Krastanov 2D --> 3D type mechanism with the transition to 3D growth occurring at approximate to 10-15 Angstrom . The mechanism changes to Frank van der Merwe (FM)/layer-by-layer growth a bove 800 degrees C. The growth of AlN on GaN occurred via a FM layer-by-lay er mechanism within the 750-900 degrees C temperature range investigated. W e propose a model based on the interaction of ammonia and atomic hydrogen w ith the GaN/AlN surfaces which indicates that the surface kinetics of hydro gen desorption and ammonia decomposition are the factors that determine the GaN growth mechanism. (C) 1999 American Institute of Physics. [S0021-8979( 99)08521-7].