Sw. King et al., X-ray photoelectron spectroscopy analysis of GaN/(0001)AlN and AlN/(0001)GaN growth mechanisms, J APPL PHYS, 86(10), 1999, pp. 5584-5593
The mechanisms of growth of GaN on AlN and AlN on GaN via gas source-molecu
lar beam epitaxy with NH3 as the nitrogen source have been investigated usi
ng x-ray photoelectron spectroscopy, low energy electron diffraction, and A
uger electron spectroscopy. The growth of GaN on AlN at low temperatures (6
50-750 degrees C) occurs via a Stranski-Krastanov 2D --> 3D type mechanism
with the transition to 3D growth occurring at approximate to 10-15 Angstrom
. The mechanism changes to Frank van der Merwe (FM)/layer-by-layer growth a
bove 800 degrees C. The growth of AlN on GaN occurred via a FM layer-by-lay
er mechanism within the 750-900 degrees C temperature range investigated. W
e propose a model based on the interaction of ammonia and atomic hydrogen w
ith the GaN/AlN surfaces which indicates that the surface kinetics of hydro
gen desorption and ammonia decomposition are the factors that determine the
GaN growth mechanism. (C) 1999 American Institute of Physics. [S0021-8979(
99)08521-7].