Atomic force microscopy measurements were carried out between zirconia and
alpha-alumina colloids over a wide pH range and in 1x10(-4) M sodium chlori
del aqueous solution. The electrophoretic mobility and potentiometric titra
tions were performed on the zirconia and alpha-alumina colloid samples, res
pectively. The electrical double-layer forces measured by atomic force micr
oscopy were related to the zeta potentials and the isoelectric point of the
both mineral dioxides, determined from the electrophoretic mobility measur
ements. (C) 1999 American Institute of Physics. [S0021-8979(99)05221-4].