Study of the solid-liquid equilibrium in mixed alkaline earth fluorohalides

Citation
H. Hagemann et al., Study of the solid-liquid equilibrium in mixed alkaline earth fluorohalides, J THERM ANA, 57(1), 1999, pp. 193-202
Citations number
22
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
57
Issue
1
Year of publication
1999
Pages
193 - 202
Database
ISI
SICI code
1388-6150(1999)57:1<193:SOTSEI>2.0.ZU;2-X
Abstract
We have studied the solid-liquid equilibrium of the system Sr1-yBayFCl1-xBr x using DTA and X-ray diffraction techniques. The entire composition range in this system yields solid solutions which crystallize in the PbFCl (Matlo ckite) structure type. The melting points of the entire composition range h ave been parametrized (within 5 degrees C rms error) using a biquadratic fi t of the available data obtained by experiment and from the literature.