Laponite: What is the difference between a gel and a glass?

Citation
D. Bonn et al., Laponite: What is the difference between a gel and a glass?, LANGMUIR, 15(22), 1999, pp. 7534-7536
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
15
Issue
22
Year of publication
1999
Pages
7534 - 7536
Database
ISI
SICI code
0743-7463(19991026)15:22<7534:LWITDB>2.0.ZU;2-J
Abstract
Solutions of the synthetic clay Laponite are strongly viscoelastic, even at very low particle concentrations. The formation of a gel, evidenced by the existence of a fractal network, has been invoked in explaining the viscoel asticity. We study the structure and viscosity of Laponite using static lig ht scattering and rheometry. Contrary to previous observations, we find no evidence of a fractal-like organization of the colloidal particles, provide d the dispersion is prepared carefully. The results show that there is no r elation between the apparent fractal dimension and the viscoelasticity, A p ossible interpretation of our results is that Laponite solutions form collo idal glasses, rather than gels.