J. Cowen et al., The use of organic accepters as ligands for paramagnetic metal centers: a new spin on charge-transfer solids, MOL CRYST A, 334, 1999, pp. 825-844
Citations number
55
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
Low temperature solution routes are being used to prepare solids with organ
ic accepters directly coordinated to paramagnetic transition metals. This r
esearch is currently focused on the elaboration of "hybrid" solids that con
tain TCNQ radicals. Magnetic and conductivity data regarding the nature of
Cu(TCNQ) and several M(TCNQ)(2) compounds will be summarized and discussed.