Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)](2)[Cr(CN)(6)]center dot H2O

Authors
Miyasaka, H Okawa, H Matsumoto, N
Citation
H. Miyasaka et al., Ferrimagnetic property of two-dimensional layered compound K[Mn(3-MeOsalen)](2)[Cr(CN)(6)]center dot H2O, MOL CRYST A, 334, 1999, pp. 1015-1023
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X → ACNP
Volume
334
Year of publication
1999
Part
2
Pages
1015 - 1023
Database
ISI
SICI code
1058-725X(1999)334:<1015:FPOTLC>2.0.ZU;2-X
Abstract
A series of bimetallic compounds of the general formula K[Mn(3-MeOsalen)](2 )[M(CN)(6)] (M = Co3+, Fe3+, Mn3+, Cr3+) has a similar 2-D network structur e but their magnetic properties vary depending upon the nature of the metal ion of [M(CN)(6)](3-) and the interlayer magnetic interaction. The magneti c property of K[Mn(3-MeOsalen)](2)[Cr(CN)(6)]. H2O shows a ferrimagnetic na ture arising from an intralayer ferrimagnetic ordering due to the antiferro magnetic spin arrangement of neighboring high spin Mn3+ and Cr3+, and an in terlayer ferromagnetic interaction.