Citation
M. Takahashi et al., Nonlinear optical property of poly(phenylenevinylene) bearing pi-conjugated radicals, MOL CRYST A, 334, 1999, pp. 31-39
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X
→ ACNP
Volume
334
Year of publication
1999
Part
1
Pages
31 - 39
Database
ISI
SICI code
1058-725X(1999)334:<31:NOPOPB>2.0.ZU;2-5
Abstract
The third order nonlinear optical susceptibility, chi((3)), of an open-shel
l and alternant polymer based on a pi-conjugated polymer poly(1,2-phenylene
vinylene) bearing phenoxylradicals at 4-position, was evaluated. The real a
nd imaginary parts of chi((3)) of the poly(1,2-phenylenevinylene) derivativ
e were enhanced three orders of magnitude at ca. 680 nm and reached ca. 10(
-9) esu due to the phenoxyl radical formation.