High-spin p-doped arylamine polymers

Authors
Bushby, RJ Gooding, D Thornton-Pett, M Vale, ME
Citation
Rj. Bushby et al., High-spin p-doped arylamine polymers, MOL CRYST A, 334, 1999, pp. 167
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X → ACNP
Volume
334
Year of publication
1999
Part
1
Database
ISI
SICI code
1058-725X(1999)334:<167:HPAP>2.0.ZU;2-4
Abstract
A method has been developed for quantitatively p-doping conjugated polymers based on an expanded m-phenylenediamine motif. This produces a disperse po pulation of high-spin species. However, these clusters of ferromagnetically coupled spins are not quite as large as would be expected on the basis of the molar mass/molar mass distribution of the polymers.