Mc. Kuchta et al., Structural characterization of an ordered crystalline modification of [In(SePh)(3)](infinity), NEW J CHEM, 23(10), 1999, pp. 957-959
A triclinic modification of [In(SePh)(3)](infinity) has been structurally c
haracterized by X-ray diffraction, demonstrating that it is chemically dist
inct from a previously reported monoclinic form. Thus, triclinic [In(SePh)(
3)](infinity) is crystallographically ordered and contains five-coordinate
trigonal bipyramidal indium centers with asymmetrically bridging [SePh] lig
ands, whereas the monoclinic form is disordered and contains six-coordinate
octahedral indium centers with symmetrically bridging [SePh] ligands.