Structural characterization of an ordered crystalline modification of [In(SePh)(3)](infinity)

Authors
Kuchta, MC Rheingold, AL Parkin, G
Citation
Mc. Kuchta et al., Structural characterization of an ordered crystalline modification of [In(SePh)(3)](infinity), NEW J CHEM, 23(10), 1999, pp. 957-959
Citations number
19
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
10
Year of publication
1999
Pages
957 - 959
Database
ISI
SICI code
1144-0546(199910)23:10<957:SCOAOC>2.0.ZU;2-U
Abstract
A triclinic modification of [In(SePh)(3)](infinity) has been structurally c haracterized by X-ray diffraction, demonstrating that it is chemically dist inct from a previously reported monoclinic form. Thus, triclinic [In(SePh)( 3)](infinity) is crystallographically ordered and contains five-coordinate trigonal bipyramidal indium centers with asymmetrically bridging [SePh] lig ands, whereas the monoclinic form is disordered and contains six-coordinate octahedral indium centers with symmetrically bridging [SePh] ligands.