Synthesis and molecular structure of bis(pyrazolyl)(3,5-di-tert-butylpyrazolyl)hydroborato thallium: a hetero-tris(pyrazolyl)hydroborato ligand derived from two different pyrazoles

Authors
Ghosh, P Churchill, DG Rubinshtein, M Parkin, G
Citation
P. Ghosh et al., Synthesis and molecular structure of bis(pyrazolyl)(3,5-di-tert-butylpyrazolyl)hydroborato thallium: a hetero-tris(pyrazolyl)hydroborato ligand derived from two different pyrazoles, NEW J CHEM, 23(10), 1999, pp. 961-963
Citations number
29
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
10
Year of publication
1999
Pages
961 - 963
Database
ISI
SICI code
1144-0546(199910)23:10<961:SAMSOB>2.0.ZU;2-R
Abstract
The hetero-tris(pyrazolyl)hydroborato thallium complex [HB(pz)(2)(pz(Bu2t)) ]Tl, derived from two different pyrazoles, may be obtained by the reaction of LiBH4 with a mixture of pyrazole and 3,5-di-tert-butylpyrazole, followed by treatment with Tl(O2CMe).