Low-energy electron diffraction (LEED) studies of Pt(111)-(root 3 x root 3)
R30 degrees-Xe at 80 K and 110 K indicate that the Xe adsorption site is on
top of the Pt atoms with a Xe-Pt distance of 3.4 Angstrom. The substrate s
tructure is essentially unrelaxed with respect to die bulk. These results c
ontrast with an earlier spin-polarized LEED study which indicated that holl
ow sites are occupied in this structure. The low-coordination-site geometry
for Xe is discussed in the context of earlier studies of Xe adsorption. [S
0163-1829(99)03939-9].