Static light scattering measurements along a critical decomposition line of a ternary liquid mixture

Citation
O. Muller et J. Winkelmann, Static light scattering measurements along a critical decomposition line of a ternary liquid mixture, PHYS REV E, 60(4), 1999, pp. 4453-4459
Citations number
22
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
60
Issue
4
Year of publication
1999
Part
B
Pages
4453 - 4459
Database
ISI
SICI code
1063-651X(199910)60:4<4453:SLSMAA>2.0.ZU;2-Y
Abstract
In the present paper we publish results of static light scattering measurem ents in the ternary system N,N-dimetylformamide+n-heptane+toluene. We deter mined the critical decomposition line in a concentration range of 0 up to 2 5 mole-% toluene. In seven mixtures along this line we obtained the correla tion length of fluctuations and the generalized osmotic susceptibility as a function of the temperature. We apply simple, power laws to calculate the critical exponents of both properties. The determined exponents show a syst ematic growth if the fraction of the third component increases. This growth exceeds the values for critical exponents that were predicted by the criti cal exponent renormalization. [S1063-651X(99)09810-4].