This investigation deals with the morphology and tensile behavior of polyst
yrene/low density polyethylene blends compatibilized by hydrogenated styren
e-b-butadiene-b-styrene triblock copolymer. The stress-strain measurements
indicate that blends with excellent toughness were achieved, due to the com
patibilizing role of the triblock copolymer in the system. The morphology o
f the blends was observed by scanning electron microscopy (SEM), and the re
sults show that the state of polystyrene changes from continuous phase to d
ispersed phase with increasing LDPE content. The correlation between mechan
ical properties and morphology is discussed. The morphologies of the tensil
e bars were also examined by SEM, and the deformation mechanisms of the ble
nd were further analysed according to fractography. (C) 1999 Society of Che
mical Industry.