The "supercompressed" state of matter as an investigation object in high-pressure chemistry

Authors
Citation
Kn. Semenenko, The "supercompressed" state of matter as an investigation object in high-pressure chemistry, RUSS CHEM B, 48(8), 1999, pp. 1425-1430
Citations number
18
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
8
Year of publication
1999
Pages
1425 - 1430
Database
ISI
SICI code
1066-5285(199908)48:8<1425:T"SOMA>2.0.ZU;2-S
Abstract
The prospects of a new line of research in high-pressure chemistry are disc ussed, which is associated with investigations of chemical reactions accomp anied by large volume effects at ambient pressure and, hence, resulting in greater compressibilities of the reaction products. The compounds formed by intercalation of alkali metals in graphite and intermetallic compounds for med between alkali metals and silver or Group V metals (Sb, Pi), which crys tallize with the BiF3 structural type, are considered as examples of "chemi cal compression.".