A study of the adsorption properties of the hypercross-linked polystyrene sorbents Styrosorb by gas chromatography. Effect of the conditioning temperature

Authors
Belyakova, LD Kurbanbekov, E Larionov, OG Tsyurupa, MP Davankov, VA
Citation
Ld. Belyakova et al., A study of the adsorption properties of the hypercross-linked polystyrene sorbents Styrosorb by gas chromatography. Effect of the conditioning temperature, RUSS CHEM B, 48(8), 1999, pp. 1484-1487
Citations number
10
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
8
Year of publication
1999
Pages
1484 - 1487
Database
ISI
SICI code
1066-5285(199908)48:8<1484:ASOTAP>2.0.ZU;2-D
Abstract
The effect of the conditioning temperature of the hypercross-linked polysty rene sorbents Styrosorb on the retention of n-hexane, benzene, and acetone was studied by gas chromatography. The rigid but mobile structure of 100% c ross-linked polymers with a specific surface area of 300-500 m(2) g(-1) pre pared in cyclohexane slightly shrinks by conditioning above 200 degrees C. This results in a significant increase in the specific retention volumes of the adsorbates. The commercial hypercross-linked sorbents MN-100 and MN-20 0 with specific surface areas of similar to 1000 m(2) g(-1) retain their st ructure up to 250 degrees C.