Synthesis of vicinal bishydroxylamine

Authors
Ovcharenko, VI Fokin, SV Romanenko, GV Korobkov, IV Rey, P
Citation
Vi. Ovcharenko et al., Synthesis of vicinal bishydroxylamine, RUSS CHEM B, 48(8), 1999, pp. 1519-1525
Citations number
31
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
8
Year of publication
1999
Pages
1519 - 1525
Database
ISI
SICI code
1066-5285(199908)48:8<1519:SOVB>2.0.ZU;2-6
Abstract
Reduction of 2,3-dimethyl-2,3-dinitrobutane with Zn in aqueous ethanol in t he presence of NH4Cl affords 2,3-bis(hydroxylamino)-2,3-dimethylbutane toge ther with 2,3-diamino-2,3-dimethylbutane and complex Zn salts. A modified p rocedure was developed for the synthesis of bishydroxylamine, which involve s reduction in a Zn/NH4Cl/THF-H2O system.