Reaction or perfluoro-2-methylpent-2-ene with ethylenediamine and hexamethylenediamine

Authors
Furin, GG Gatilov, YV Bagryanskaya, IY Zhuzhgov, EL
Citation
Gg. Furin et al., Reaction or perfluoro-2-methylpent-2-ene with ethylenediamine and hexamethylenediamine, RUSS CHEM B, 48(8), 1999, pp. 1558-1562
Citations number
18
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
8
Year of publication
1999
Pages
1558 - 1562
Database
ISI
SICI code
1066-5285(199908)48:8<1558:ROPWEA>2.0.ZU;2-6
Abstract
Reaction of perfluoro-2-methylpent-2-ene: with ethylenediamine and hexameth ylenediamine results in 9-fluoro-5,9-bis(pentafluoroethyl)-6,8,8-tris(trifl uoromethyl)-1,4-diazabicyclo[5.2.0]nona-4,6-diene, whose structure was conf irmed by X-ray analysis, and 11-pentafluoroethyl-10-trifluoromethl-1,8-diaz abicyclo[7.2.0]undeca-8,10-diene, respectively. The reaction pathways are d iscussed.