Tetraphenylarsonium diazidotriphenylstannate

Authors
Benetollo, F Bombieri, G Alonzo, G Bertazzi, N
Citation
F. Benetollo et al., Tetraphenylarsonium diazidotriphenylstannate, ACT CRYST C, 55, 1999, pp. 1664-1665
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
10
Pages
1664 - 1665
Database
ISI
SICI code
0108-2701(19991015)55:<1664:TD>2.0.ZU;2-7
Abstract
The triphenyltin-azide anion of the title tetraphenylarsonium salt, [As(C6H 5)(4)][Sn(C6H5)(3)(N-3)(2)], shows approximately trigonal-bipyramidal coord ination geometry around the metal ion, with the azide moieties in axial pos itions having equal bond distances [Sn-N 2.278 (5) and 2.281(6) Angstrom] b ut different bond angles [Sn-N-N 117.4(4) and 125.2(5)degrees] to the tin. The cation has its usual tetrahedral geometry.