Co-Fe-Mo-Mn-Si-B metallic glass ribbon (Vitrovac 6030) was subjected to the
isothermal annealing at temperatures in the range 523-873 K so as to produ
ce a series of samples with gradually coarser microstructure. For this seri
es of samples a giant increase in the coercivity, exceeding three orders of
magnitude, is observed. This increase is interpreted in terms of the stren
gthening of the pinning effect of the nanocrystalline structure on the movi
ng domain walls. It is shown that the anisotropy of tl le created crystalli
tes is mainly responsible for the increase in the pinning force since the e
ffective anisotropy seen by the wall becomes larger and larger with the gra
dual increase in the density and size of the grown particles.