Possible air separations with superconducting membranes

Citation
Rd. Gordon et El. Cussler, Possible air separations with superconducting membranes, AICHE J, 45(11), 1999, pp. 2313-2325
Citations number
31
Categorie Soggetti
Chemical Engineering
Journal title
AICHE JOURNAL
ISSN journal
00011541 → ACNP
Volume
45
Issue
11
Year of publication
1999
Pages
2313 - 2325
Database
ISI
SICI code
0001-1541(199911)45:11<2313:PASWSM>2.0.ZU;2-W
Abstract
Permeabilities of oxygen, nitrogen and helium across porous, super-conducti ng membranes with 5- mu m pores are consistent with those across nonsuperco nducting membranes with well-defined pores of similar sizes. This is true b oth at ambient and super conducting temperatures. Transport can occur by Kn udsen diffusion, Poiseuille flow, capillary condensation, and turbulent flo w. There is no evidence of surface diffusion. Theoretical considerations of superconducting membranes are consistent with these results, indicating wh en superconductivity might play a role. However, past reports concerning ai r separation with superconducting membranes with these micrometer-sized por es are questionable.