Estimation of pore water concentrations from DGT profiles: A modelling approach

The technique of Diffusional Gradients in Thin-films (DGT) can be used in s itu to obtain high resolution profiles of trace-metals in sediment pore wat ers. Substances sampled by DGT continuously diffuse through a 'diffusion la yer' comprising a hydrogel prior to being immobilized by binding to a resin layer. DGT therefore measures a time averaged flux from the pore water to the resin. Interpretation of this flux as pore water concentration is probl ematic for two reasons. Firstly, the pore water concentration adjacent to t he sampler may become depleted by the DGT induced flux. Secondly, if there are steep vertical chemical gradients in the pore waters, they may relax by diffusion along the gradient within the gel layer. The extent of relaxatio n depends on the diffusion coefficient, gradient steepness, and diffusion l ayer thickness. Two dimensional (2D) numerical models of DGT deployments in horizontally uniform sediments were used to investigate to what extent DGT measured profiles accurately reproduced (a) the shape of pore water concen tration profiles, and (b) the magnitude of pore water concentrations. A met hod is developed which translates high resolution DGT measured flux profile s into reliable estimates of pore water concentrations. Linear relationship s are given which estimate the minimum DGT measured peak width (as a functi on of diffusion layer thickness) that ensures accurate reproduction of the shape and the magnitude of peaks in pore water concentrations. Peaks in DGT profiles obtained from assemblies with diffusion layer thicknesses of 0.3 mm (0.5 mm) should be at least 1.2 mm (1.8 mm) wide for their shape to refl ect accurately their true shape in the pore water, and at least 1.7 mm (2.7 mm) wide to ensure the peak concentration is accurately estimated.