EQCM characterization of self-assembled kinetics of 4-pyridyl hydroquinoneat Pt surface and its ion transfer in electrochemical redox

Citation
L. Niu et al., EQCM characterization of self-assembled kinetics of 4-pyridyl hydroquinoneat Pt surface and its ion transfer in electrochemical redox, ELECTROANAL, 11(15), 1999, pp. 1112-1115
Citations number
28
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ELECTROANALYSIS
ISSN journal
10400397 → ACNP
Volume
11
Issue
15
Year of publication
1999
Pages
1112 - 1115
Database
ISI
SICI code
1040-0397(199911)11:15<1112:ECOSKO>2.0.ZU;2-7
Abstract
The adsorbed kinetics, proton transportation in electrochemical redox proce ss of 4-pyridyl hydroquinone (4PHQ) self-assembled monolayer (SAM) modified Pt electrode were studied by electrochemical quartz crystal microbalance ( EQCM) in situ. It proved that the electrode was modified by a monolayer and underwent a rapid electron transfer. It was a slow adsorbed kinetic proces s. The ion transfer in the electrochemical redox at the SAM-modified electr ode surface mainly involved into the hydrate hydrogen ion.