L. Niu et al., EQCM characterization of self-assembled kinetics of 4-pyridyl hydroquinoneat Pt surface and its ion transfer in electrochemical redox, ELECTROANAL, 11(15), 1999, pp. 1112-1115
The adsorbed kinetics, proton transportation in electrochemical redox proce
ss of 4-pyridyl hydroquinone (4PHQ) self-assembled monolayer (SAM) modified
Pt electrode were studied by electrochemical quartz crystal microbalance (
EQCM) in situ. It proved that the electrode was modified by a monolayer and
underwent a rapid electron transfer. It was a slow adsorbed kinetic proces
s. The ion transfer in the electrochemical redox at the SAM-modified electr
ode surface mainly involved into the hydrate hydrogen ion.