Stanna-closo-dodecaborate: A nucleophile in transition metal chemistry

Authors
Wesemann, L Marx, T Englert, U Ruck, M
Citation
L. Wesemann et al., Stanna-closo-dodecaborate: A nucleophile in transition metal chemistry, EUR J INORG, (9), 1999, pp. 1563-1566
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
9
Year of publication
1999
Pages
1563 - 1566
Database
ISI
SICI code
1434-1948(199909):9<1563:SANITM>2.0.ZU;2-E
Abstract
Reactions of the stannaborate salt [NBu4](2)[SnB11H11] (1) with the organom etallic electrophiles [CpFe(CO)(2)Br], [(C7H7)Mo(CO)(2)I], and [CpNi(PPh3)C l] resulted in substitution of the halide to give the stannaborate coordina tion products [NBu4][CpFe(CO)(2)(SnB11H11)] (2), [NBu4][(C7H7)Mo(CO)(2)(SnB 11H11)] (3), and [NBu4][CpNi(PPh3)(SnB11H11)] (4) in high yields. Single cr ystals of the air- and moisture-stable products have been characterized by X-ray crystal structure analyses.