V. Felis et al., Three-step catalytic detoxification process of wastewater containing chlorinated aromatic compounds: Experimental results and modeling issues, IND ENG RES, 38(11), 1999, pp. 4213-4219
Detoxification of water containing chlorinated aromatic compounds is perfor
med in a single fixed bed using a periodic sequence of three steps: transie
nt adsorption, catalytic hydrogenation, and thermal regeneration. The solid
is both the adsorbent (activated carbon) and the catalyst (2.6% ruthenium
loading). For chlorophenols, the end products are cyclohexanol and sodium c
hloride diluted in less than 2% of the amount of processed water. Adsorptio
n is the critical step. The whole breakthrough curve is easily modeled. Con
versely, the model fails to describe the early beginning which governs the
purity of the effluent. The reaction step is performed under mild condition
s (T < 353 K, P < 0.4 MPa) and is governed by the transient desorption of t
he pollutant, the catalytic reaction, and the mass-transfer processes. Ther
mal regeneration under hydrogen flow restores the adsorbent capacity and ca
talytic activity.