An unusual o-metallated pyridyl dirhodium(II) complex: [Rh-2{mu-(C5H3N)NH(C5H4N)}(2){eta(2)-(C5H4N)NH(C5H4N}(2)]Cl-2 center dot CH3OH

Authors
Cotton, FA Murillo, CA Stiriba, SE
Citation
Fa. Cotton et al., An unusual o-metallated pyridyl dirhodium(II) complex: [Rh-2{mu-(C5H3N)NH(C5H4N)}(2){eta(2)-(C5H4N)NH(C5H4N}(2)]Cl-2 center dot CH3OH, INORG CH C, 2(10), 1999, pp. 463-464
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
10
Year of publication
1999
Pages
463 - 464
Database
ISI
SICI code
1387-7003(199910)2:10<463:AUOPDC>2.0.ZU;2-N
Abstract
Reaction of Rb-2(O2CMe)(4) and bis(2-pyridyl)amine, Hdpa, followed by addit ion of CH2Cl2 led to replacement of the acetate groups by Hdpa and orthomet allation of two Hdpa pyridyl groups. The isolated complex, [Rh-2{mu-(C5H3N) NH(C5H3N)}(2)(eta(2)-(C5H4N)NH(C5H4N}(2)]Cl-2 (1), has been characterized b y X-ray crystallography, showing that the complex has two equatorially boun d Hdpa groups and two bridging orthometallated dpa anions. (C) 1999 Elsevie r Science S.A. All rights reserved.