X- and Q-band EPR on Fe-57-enriched [(C6H5)(4)As](2)[Fe-I(NO) (mnt)(2)]

Authors
Teschmit, G Kirmse, R
Citation
G. Teschmit et R. Kirmse, X- and Q-band EPR on Fe-57-enriched [(C6H5)(4)As](2)[Fe-I(NO) (mnt)(2)], INORG CH C, 2(10), 1999, pp. 465-467
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
10
Year of publication
1999
Pages
465 - 467
Database
ISI
SICI code
1387-7003(199910)2:10<465:XAQEOF>2.0.ZU;2-W
Abstract
X- and Q-band EPR spectra of the anionic 3d(7) 'low spin' (S=1/2) complex t etraphenylarsonium-bis( 1,2-dicyanoethene-1,2-dithiolato)nitrosyliron(I) en riched with Fe-57 show resolved Fe-57 and N-14 hyperfine patterns character ised by rhombic g, A(Fe) and A(N) tensors. The hyperfine parameters an used to determine the spin-density distribution in the FeNS4 unit. (C) 1999 Els evier Science S.A. All rights reserved.