Synthesis and characterization of Tc2Cl4(dppm)(2)

Authors
Freiberg, E Davison, A Jones, AG Davis, WM
Citation
E. Freiberg et al., Synthesis and characterization of Tc2Cl4(dppm)(2), INORG CH C, 2(10), 1999, pp. 516-518
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
10
Year of publication
1999
Pages
516 - 518
Database
ISI
SICI code
1387-7003(199910)2:10<516:SACOT>2.0.ZU;2-E
Abstract
The reaction of Tc2Cl4(PEt3)(4) with two equivalents of bis(diphenylphosphi no) methane (dppm) in refluxing benzene results in the formation of Tc2Cl4( dppm)(2) (1) in 61% yield. The metal-metal multiply bonded complex 1 has be en structurally and spectroscopically characterized. (C) 1999 Elsevier Scie nce S.A. All rights reserved.