Fluorination of graphitized blacks with chlorine trifluoride

Authors
Makotchenko, VG Nazarov, AS Yakovlev, II
Citation
Vg. Makotchenko et al., Fluorination of graphitized blacks with chlorine trifluoride, INORG MATER, 35(11), 1999, pp. 1186-1187
Citations number
10
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INORGANIC MATERIALS
ISSN journal
00201685 → ACNP
Volume
35
Issue
11
Year of publication
1999
Pages
1186 - 1187
Database
ISI
SICI code
0020-1685(199911)35:11<1186:FOGBWC>2.0.ZU;2-W
Abstract
Graphitized blacks prepared by destructive decomposition of the intercalati on compounds C2.14FCl0.07 . 0.12ClF(3) and C2.14FCl0.07 . 0.09CCl(4) react with chlorine trifluoride at room temperature to yield a compound with the formula C2F0.98Cl0.06 and an interlayer spacing of 6.2 Angstrom. As found b y F-19 nuclear magnetic resonance and infrared spectroscopy, this compound contains no intercalated chlorine trifluoride, presumably because of the sm all particle size of graphitized blacks.