Monte Carlo simulations of electron transport have been performed in methan
e for time resolved rf fields under conditions where negative differential
conductivity (NDC) occurs. It was found that the effect of NDC occurs follo
w frequencies as expected from the quasi stationary (temporally local) mode
l. At higher frequencies the NDC disappears gradually but the NDC behavior
is significantly different when field increases and when field decreases. I
n the latter case the NDC disappears while in the former it blends into one
maximum occurring at the point of the maximum of the electric field with a
n intermediate frequency region with asymmetric time dependence.