Polyethylene-based magnetic composites have been prepared by ethylene polym
erization on the surface of NdFeB magnets, which is previously activated by
ball milling with catalyst components. The level of magnets has been contr
olled by catalyst preparation and polymerization parameters such as Al/Ti r
atio and polymerization temperature. The coertivity and the residual magnet
izability were investigated. It was found that the magnetic properties of m
agnet powders are largely retained. In addition, in contrast to composites
prepared by melt mixing, the adhesion force between magnets and polymer mat
rix is improved significantly and better mechanical properties are expected
. (C) 1999 John Wiley & Sons, Inc.