TiO2-supported V2O5-MoO3 catalysts, having V and Mo loadings representative
of commercial SCR catalysts, are considered in this study. These catalysts
are constituted by TiO2 anatase supporting the V and Mo active components.
MoO3 acts as a "structural" promoter preventing the TiO2 matrix from sinte
ring upon vanadia addition. The Mo and V oxide are present on the catalyst
surface in the form of molybdenylic and vanadylic species, respectively, an
d the presence of polymeric MoxOy species cannot be excluded. The features
of the V and Mo surface oxide species closely resemble those observed over
the binary V2O5/TiO2 and MoO3/TiO2 catalysts, thus pointing out the vibrati
onal independence of the V and Mo surface vanadyl and molybdenyl oxide spec
ies. However, in spite of their structural and vibrational independence, th
e presence of electronic interactions between the TiO2-supported V and Mo o
xides is also apparent. These interactions may operate via the TiO2 support
or may involve mixed V-Mo surface oxide species who were, however, not obs
erved. The catalyst surface is characterized by strong acidity, probed by N
H3-TPD and FT-IR. Ammonia is coordinatively held over Lewis acid sites (ass
ociated with Ti, V, and Mo surface cation species) and is protonated as NH:
ions over Mo-OH or V-OH Bronsted sites. The addition of Mo and V causes th
e formation of Bronsted sites and of stronger Lewis acid sites, if compared
to TiO2. The V2O5-MoO3/TiO2 catalysts are very active in the reduction of
NO by NH3, and exhibit a higher reactivity with respect to the correspondin
g binary V2O5/TiO2 and MoO3/TiO2 samples. Calculations show that the reacti
vity of V and/or Mo in the ternary catalysts is higher than that measured o
ver V2O5/TiO2 and MoO3/TiO2 having the same V and Mo loading: hence it is s
uggested that a synergism operates in the SCR reaction between the V and Mo
surface oxide species. Accordingly in these catalysts molybdenum also acts
as a "chemical" promoter for the SCR reaction. On the basis of the charact
erization data, it is suggested that the observed synergism in the SCR reac
tion is related to the existence of the V-Mo electronic interactions. This
picture closely resembles that obtained in the case of the analogous V2O5-W
O3/TiO2 system and indicates that the effects of the addition of WO3 and Mo
O3 to V2O5/TiO2 are similar, both oxides acting as "chemical" promoters bes
ides playing a "structural" function as well. However the V2O5-MoO3/TiO2 sa
mples show higher formation of N2O and lower NO conversions at high tempera
tures: these differences are possibly associated with the different electro
nic characteristics of Mo compared to W and to their higher reactivity in t
he ammonia oxidation reactions. It is found that water addition in the feed
improves the catalyst performance in that it preserves high NO conversions
and high Na selectivities at high temperatures: this is due to its strong
inhibiting effect on the ammonia oxidation reactions occurring simultaneous
ly with the SCR reactions. (C) 1999 Academic Press.