Effect of competition between catalytic particles C on the rate of the reversible diffusion-controlled reaction A+C reversible arrow B+C

Authors
Felderhof, BU Jones, RB
Citation
Bu. Felderhof et Rb. Jones, Effect of competition between catalytic particles C on the rate of the reversible diffusion-controlled reaction A+C reversible arrow B+C, J CHEM PHYS, 111(20), 1999, pp. 9441-9445
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
111
Issue
20
Year of publication
1999
Pages
9441 - 9445
Database
ISI
SICI code
0021-9606(19991122)111:20<9441:EOCBCP>2.0.ZU;2-H
Abstract
The effect of competition between catalytic particles C on the rate of the reversible diffusion-controlled reaction A+reversible arrow B+C is studied in a self-consistent approximation. The C-particles are assumed static with random configuration. The A- and B-particles diffuse in a fluid or solid b ackground medium. Frequency-dependent effective rate coefficients are calcu lated as a function of the volume fraction of C-particles. (C) 1999 America n Institute of Physics. [S0021- 9606(99)51544-4].