An investigation of the conditions giving rise to surface reconstruction fo
r GaN grown by molecular beam epitaxy on (0 0 0 (1) over bar) bulk GaN subs
trates has been carried out. The results of different surface reconstructio
ns were investigated by supplying Ga and active nitrogen separately to GaN
surfaces. A (2 x 2) reconstruction on (0 0 0 (1) over bar)GaN substrates an
d for GaN layers grown on such substrates was observed. The (2 x 2) surface
reconstruction is stable in the presence of an active nitrogen flux at hig
h temperature, but it disappears on cooling the GaN sample below similar to
400 degrees C. The (2 x 2) reconstruction is considered to be due to an ad
ditional amount of relatively tightly bound Ga on this (1 x 1) surface. Add
ing further Ga to the (2 x 2) reconstructed surface resulted in a return to
a (1 x 1) reconstruction. (C) 1999 Elsevier Science B.V. All rights reserv
ed.