Synthesis of 3-perfluoroalkylprop-1-enes R-F-CH2-CH = CH2

Authors
Rubio, S Blancou, H Commeyras, A
Citation
S. Rubio et al., Synthesis of 3-perfluoroalkylprop-1-enes R-F-CH2-CH = CH2, J FLUORINE, 99(2), 1999, pp. 171-175
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
99
Issue
2
Year of publication
1999
Pages
171 - 175
Database
ISI
SICI code
0022-1139(199911)99:2<171:SO3R=C>2.0.ZU;2-J
Abstract
The reactions of perfluoroalkyl iodides with allylbromide or chloride, in t he presence of solid potassium hydroxide KOH give 3-perfluoroalkylprop-1-en es RFCH2CH=CH2 in good yields under mild conditions. This reaction represen ts a synthetically viable and convenient route to such compounds. (C) 1999 Elsevier Science S.A. All rights reserved.