Fluorous biphasic hydrogenation of 1-alkenes using novel fluorous derivatives of Wilkinson's catalyst

Authors
Richter, B Deelman, BJ van Koten, G
Citation
B. Richter et al., Fluorous biphasic hydrogenation of 1-alkenes using novel fluorous derivatives of Wilkinson's catalyst, J MOL CAT A, 145(1-2), 1999, pp. 317-321
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
145
Issue
1-2
Year of publication
1999
Pages
317 - 321
Database
ISI
SICI code
1381-1169(19990908)145:1-2<317:FBHO1U>2.0.ZU;2-8
Abstract
A novel approach for the easy attachment of fluorous tails to aryl phospine s has been developed, leading to a new fluorous alkylsilyl-substituted tria ryl phospines P(C6H4SiMe2Rf-4)(3)(R-f = -(CH2)(2)(CF2)(n)CF3; n= 5, 7). The derived fluorous tris(aryl phospine)rhodium(I) chloride complexes, being f luorous analogs of Wilkinson's catalyst, show high activity in hydrogenerat ion of 1-alkenes under fluorous biphasic (FBS) conditions and can be effect ively recycled. (C) 1999 Elsevier Science B.V. All rights reserved.