Magnetic field effect on the micellar (C-60)(n)(center dot-)-pyrene(centerdot+) radical-pair system

Citation
M. Haldar et al., Magnetic field effect on the micellar (C-60)(n)(center dot-)-pyrene(centerdot+) radical-pair system, J PHOTOCH A, 127(1-3), 1999, pp. 7-12
Citations number
43
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
ISSN journal
10106030 → ACNP
Volume
127
Issue
1-3
Year of publication
1999
Pages
7 - 12
Database
ISI
SICI code
1010-6030(199910)127:1-3<7:MFEOTM>2.0.ZU;2-R
Abstract
We report for the first time a magnetic field effect on radical pair recomb ination involving fullerene clusters in a fluorinated micelle. It is found that the rate of decay of radicals increases with increasing external magne tic field strength. The effect at high field is attributed to the g-anisotr opy-induced relaxation mechanism. (C) 1999 Elsevier Science S.A. All rights reserved.