Fourier Transform infrared spectrometry has been used to study the vibratio
nal spectroscopy of water clusters prepared in a supersonic expansion. The
clusters are assigned as being composed of 10-100 waters based on considera
tion of the free OH and bound OH vibrations and the experimental conditions
used. Four vibrational features were observed simultaneously including the
bend, free OH stretch, bound OH stretch, and an unresolved group of interm
olecular vibrations. No absorption features were observed between 4000 and
8000 cm(-1). This is the first observation of the bending vibration for any
size gas-phase water cluster.