The electroluminescence and photophysical properties of a series of 11 poly
quinolines were investigated and used to explore the effects of molecular a
nd supramolecular structures on the light-emitting proper ties of polymers.
Thin films of the polyquinolines have photoluminescence quantum yields bet
ween 2 and 30% and unusually long excited-state lifetimes of 2.4-5.2 ns. El
ectroluminescence colors spanning blue, green, yellow, orange, and red were
obtained through regulation of the molecular and supramolecular structures
of the excimer- and aggregate-forming polyquinolines. ITO/hole transport l
ayer/polyquinoline/Al light-emitting diodes fabricated and evaluated in air
had electroluminescence quantum efficiencies between 0.02 and 1% and lumin
ance levels of up to 280 cd/m(2) at a current density of 100 mA/cm(2). The
electroluminescence efficiency approximately scaled linearly with the photo
luminescence quantum yield. Favorable reaction at the aluminum/polyquinolin
e interface is proposed to account for the efficient electron injection and
device performance in spite of the large (1.5-1.9 eV) energetic barrier to
electron injection. These results provide new insights into the design of
efficient light-emitting polymer materials and devices for optoelectronic a
pplications.