The effect of nitrogen and carbon on the strengthening of the austenitic st
eel Cr18Ni16Mn10 by grain boundaries is studied. It is established in accor
dance with previous results that, in contrast to carbon, nitrogen markedly
increases the coefficient k in the Hall-Fetch equation. Because of a pronou
nced planar slip induced by nitrogen and the absence of ally noticeable seg
regation of nitrogen atoms at the grain boundaries, nitrogen austenite pres
ents an excellent object for testing different existing models of grain bou
ndary strengthening (pile-up of dislocations, grain boundary dislocation so
urces, work hardening). Based on the analysis of available data and measure
ments of interaction between nitrogen or carbon atoms and dislocations it i
s shown that the nitrogen effect can be attributed to a strong blocking of
dislocation sources in grains adjacent to those where the slip started. (C)
1999 Elsevier Science S.A. All rights reserved.