Effect of hydrazinium monoperchlorate on thermal decomposition of hydroxylammonium perchlorate

Citation
Gn. Nechiporenko et al., Effect of hydrazinium monoperchlorate on thermal decomposition of hydroxylammonium perchlorate, RUS J AP CH, 72(7), 1999, pp. 1148-1151
Citations number
6
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
72
Issue
7
Year of publication
1999
Pages
1148 - 1151
Database
ISI
SICI code
1070-4272(199907)72:7<1148:EOHMOT>2.0.ZU;2-U
Abstract
The kinetics of gas liberation from mixtures of hydroxylammonium perchlorat e and hydrazinium monoperchlorate in the temperature range 60-80 degrees C was studied at low extents of thermal decomposition. The kinetic parameters were determined of the Arrhenius equation describing gas liberation in the rmal decomposition of hydroxylammonium perchlorate samples. The reaction of hydroxylammonium perchlorate, containing up to 10 wt % hydrazinium monoper chlorate, with tetramethylenetetranitroamine (octogen) at weight ratio hydr oxylammonium perchlorate : octogen = 3 : 2 was studied.