This paper presents the results of a systematic study of porous silicon lig
ht emitting diodes (LEDs). Porous silicon pn junction LEDs, both patterned
and unpatterned, were fabricated using the standard anodization method as w
ell as a novel technique developed for the anodization of heavily doped pn
junction structures. The current-voltage, photoluminescence and electrolumi
nescence properties of the various porous silicon pn junction LEDs were inv
estigated. The devices fabricated by the standard method show electrolumine
scence only under reverse bias conditions. The pn junctions fabricated by t
he novel anodization technique show electroluminescence under forward bias
conditions. The light emission mechanism in these devices is believed to be
due to electron-hole injection in the silicon nanostructures forming the p
orous silicon material.