R. Casalini et al., Organic vapour sensing using thin films of a co-ordination polymer: comparison of electrical and optical techniques, SENS ACTU-B, 57(1-3), 1999, pp. 28-34
Langmuir-Blodgett (LB) films of the co-ordination polymer, poly(CuMBSH), ha
ve been used as the sensing layer for the detection of organic vapours (ben
zene, ethanol, toluene, acetonitrile and water) using the techniques of sur
face plasmon resonance (SPR) and admittance spectroscopy. Reversible change
s in the optical and electrical behaviour, respectively, were observed. For
both methods, the results were interpreted in terms of a bulk dissolution
of vapour in the polymer film. A comparison of the two techniques is given.
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