Mossbauer spectroscopy to characterize iron sulphides

Citation
Fb. Waanders et al., Mossbauer spectroscopy to characterize iron sulphides, S AFR J SCI, 95(9), 1999, pp. 387-390
Citations number
14
Categorie Soggetti
Multidisciplinary,Multidisciplinary
Journal title
SOUTH AFRICAN JOURNAL OF SCIENCE
ISSN journal
00382353 → ACNP
Volume
95
Issue
9
Year of publication
1999
Pages
387 - 390
Database
ISI
SICI code
0038-2353(199909)95:9<387:MSTCIS>2.0.ZU;2-G
Abstract
Mossbauer spectroscopy, SEM and microprobe analyses were used to study a na turally occurring and a synthetically produced mineral. Valleriite is a com plex layered mineral and varies on the basis of crystal structure, composit ion and occurrence. The Mossbauer technique was used to characterize and de scribe it. The valleriite studied contains iron in the 2+ and 3+ oxidation states and the proportions of the two states were calculated. Pyrite was sy nthesized by reacting Fe2+ and S2O32- and the compound thus produced can be used in the manufacture of thermal batteries. The Mossbauer, SEM and X-ray data of the synthesized pyrite were compared with information on naturally occurring pyrite and other iron sulphides.