Highly regioselective silaboration of 3-substituted 1,2-dienes catalyzed by palladium/2,6-xylyl isocyanide

Authors
Suginome, M Ohmori, Y Ito, Y
Citation
M. Suginome et al., Highly regioselective silaboration of 3-substituted 1,2-dienes catalyzed by palladium/2,6-xylyl isocyanide, SYNLETT, (10), 1999, pp. 1567-1568
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
10
Year of publication
1999
Pages
1567 - 1568
Database
ISI
SICI code
0936-5214(199910):10<1567:HRSO31>2.0.ZU;2-L
Abstract
Regioselective silaboration of 3-substituted 1,2-dienes was efficiently cat alyzed by palladium/2,6-xylyl isocyanide complex, affording an adduct, in w hich the boryl and silyl groups were introduced at the central allenyl carb on and at the substituted allenyl carbon, respectively.