N-trityl-aziridinyl(diphenyl)methanol as an effective catalyst in the enantioselective addition of diethylzinc to aldehydes

Citation
Cf. Lawrence et al., N-trityl-aziridinyl(diphenyl)methanol as an effective catalyst in the enantioselective addition of diethylzinc to aldehydes, SYNLETT, (10), 1999, pp. 1571-1572
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
10
Year of publication
1999
Pages
1571 - 1572
Database
ISI
SICI code
0936-5214(199910):10<1571:NAAECI>2.0.ZU;2-K
Abstract
High levels of enantioselectivity have been achieved in the diethylzinc add ition to both aromatic and aliphatic aldehydes, employing N-trityl-aziridin yl(diphenyl)methanol as the chiral catalyst. The R- and S-antipodes of the catalyst can readily be prepared from D- acid L-serine, respectively.