Diastereoselective photocyclization to dihydroindolinols

Citation
M. Seiler et al., Diastereoselective photocyclization to dihydroindolinols, SYNLETT, (10), 1999, pp. 1588-1590
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
10
Year of publication
1999
Pages
1588 - 1590
Database
ISI
SICI code
0936-5214(199910):10<1588:DPTD>2.0.ZU;2-P
Abstract
Photocyclization of substituted o-aminophenylketone 1b leads in high yields to indolinol 3b. Depending upon the substituent R-2 and on the solvent eit her cis-products (10: R-2=COX) or trans-products (12. R-2=Ph) are formed pr edominantly.