Synthesis of C1-C32 fragment of aza-solamin, an unnatural analogue of the annonaceous acetogenin solamin

Authors
Pichon, M Hocquemiller, R Figadere, B
Citation
M. Pichon et al., Synthesis of C1-C32 fragment of aza-solamin, an unnatural analogue of the annonaceous acetogenin solamin, TETRAHEDR L, 40(49), 1999, pp. 8567-8570
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
49
Year of publication
1999
Pages
8567 - 8570
Database
ISI
SICI code
0040-4039(199912)40:49<8567:SOCFOA>2.0.ZU;2-K
Abstract
A synthesis of the skeleton of the pyrrolidino analogue of solamin, an anno naceous acetogenin, is presented. The configurations of four out of five st ereocenters are controlled by enantioselective aldolization and C-glycosyla tion reactions. (C) 1999 Elsevier Science Ltd. All rights reserved.